國立臺灣海洋大學助理教授 (2015─NOW)
國立中央大學研究學者 (2010─2015，科技部延攬研究學者計畫)
中央研究院/中央大學博士後研究 (2009-2010)
中央研究院國防科技役研究助理 (2003─2009)
Assistant Prof. Chih-Min Wang
MY LATEST RESEARCH
A highly stable framework of organic‐inorganic hybrid zinc phosphite (NTOU‐4) and its cobalt analogue (NTOU‐4a) were synthesized under the hydro(solvo)thermal conditions and structurally characterized by single‐crystal X‐ray diffraction. Their frameworks consisted of inorganic metallophosphite chains, in which the metal atoms were interlinked through 1H‐1,2,4‐triazole‐3,5‐diamine and 1,4‐benzenedicarboxylate linkers to form new crystalline materials.
A Highly Stable Framework of Crystalline Zinc Phosphite with Selective Removal, Recovery, and Turn‐On Sensing Abilities for Mercury Cations in Aqueous Solutions
Chih-Min Wang, Yong-Jie Lin, Ming-Feng Pan, Cheng-Kuan Su, and Tai-Yuan Lin
A Series of Organic–Inorganic Hybrid Zinc Phosphites Containing Extra-Large Channels
Chih-Min Wang, Ming-Feng Pan, Yong-Jie Lin, Mei-Ying Chung, Yuh-Sheng Wen, Yung Chang, Hsiu-Mei Lin, and Todd Hsu
Inorg. Chem., 2018, 57 (5), pp 2390–2393 DOI: 10.1021/acs.inorgchem.7b03235
We report another route for manufacturing the unprecedented example of three zeolite-related materials with extra-large-channel structures by introducing carboxylate ligands into an organically templated zinc phosphite system. Their frameworks are composed of carboxylate linkers and inorganic zinc phosphites, translating their channel windows from a square shape (NTOU-1) to rhombus forms (NTOU-2 and NTOU-3) via the replacement of organic amines or ligands under synthesis conditions otherwise identical with those used to prepare NTOU-1. The synthesis, structural diversity, photoluminescence, and adsorption properties for dye molecules and lanthanide ions are also presented.
Chemistry - A European Journal 26 May 2018 DOI: 10.1002/chem.201802455
我們實驗室的研究課題為合成具有金屬有機骨架與沸石結構特性的孔洞化合物。
目前，金屬有機骨架 (Metal organic Frameworks, MOFs) 與無機骨幹相關沸石材料為世界上兩種最熱門的研究課題之一。
相較於金屬有機骨架多變的結構特性 (化學家利用改變有機配位子影響最後的結構特性)，剛性的無機配位子與金屬離子則可以形成結構穩定的化合物。
然而，結合兩種結構特性於同一個材料的合成研究是困難，有許多合成的變因需要考慮，例如：pH值、溶解度、溫度、及有機與無機分子對金屬的競爭能力等。
本篇文章是第一個利用[1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene]有機配位子導入金屬亞磷酸鹽的例子。其特殊有機—無機混成的3D管狀孔洞結構也具有許多有趣的氣體吸附性質，例如：高的二氧化碳與低的氮氣吸附量可以進一步研究此材料分離氣體的能力。同時，此化合物除了是發藍光的材料外也可以製作成發紫白光的LED元件。
實驗室氣氛是和樂融融的；我們推崇自由的研究風氣（在相關主題下可以盡情的發揮想像力）；非常歡迎化學系；生命科學等相關科系同學與我們一起研究打拼。
目前研究主題著重於：
1. 大孔洞固態材料的合成。
2. 新發白光材料的開發。
3. 孔洞材料於藥物釋放的應用研究。
Congratulations
恭喜本實驗室范秉綸和王之伶同學的研究獲選為
Chemistry_ A European Journal的封面文章!!
Two Polymorphs of an Organic−Zincophosphate Incorporating a
Terephthalate Bridging Ligand in an Unusual Bonding Mode
Chih-Min Wang, Ming-Feng Pan, Yen-Chieh Chen, Hsiu-Mei Lin, Mei-Ying Chung, Yuh-Sheng Wen, and Kwang-Hwa Lii
Inorg. Chem., 2017, 56 (14), pp 7602–7605 DOI: 10.1021/acs.inorgchem.7b00645
Two organozincophosphate polymorphs were obtained by incorporating the terephathalate organic ligand 1,4-benzenedicarboxylate (BDC) into the inorganic structures of metal phosphates via hydro(solvo)thermal methods at different reaction temperatures and structurally characterized by single-crystal X-ray diffraction. Remarkably, the bis-monodentate BDC ligand showed a very rare modality, with a cis-coordination linkage between the metal centers and carboxyl groups. We also presented a simple approach for tuning the optical properties of the title compound from blue, red, green, yellow, and pink to white emission.